KMID : 0043319940170050327
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Archives of Pharmacal Research 1994 Volume.17 No. 5 p.327 ~ p.330
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A Regioselectio Synthesis of ¥â-Lactones; Bromolactonization of 2-Substituted-1-Cyclohexenyl-1-acetic acid
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Jew Sang-Sup
Lee Hee-Soon Koo Bon-Am
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Abstract
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Bromolactonization of 2-substituted-1-cyclohexenyl-1-acetic acids with 1, 3-dibromo-5, 5-dime-thylhydantoin 9DBH) and potsssium tertiary butoxide (t-BuOK0 in anhydrous DMF was found to proceed in a highly regioselective manner. The reaction predominantly resulted in the formation of (greater than 96%).
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KEYWORD
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Broomolactonization
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